15804-86-1

Basic information

• Product Name: ethyl 2',5'-dimethoxycinnamate
• Synonyms: ethyl 2',5'-dimethoxycinnamate
• CAS NO: 15804-86-1
• Molecular Weight: 236.268
• Mol File: 15804-86-1.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: ethyl 2',5'-dimethoxycinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2',5'-dimethoxycinnamate(15804-86-1)
• EPA Substance Registry System: ethyl 2',5'-dimethoxycinnamate(15804-86-1)

Safety Data

• Hazardous Substances Data: 15804-86-1(Hazardous Substances Data)

Upstream product

• 93-02-7 2,5-dimethoxybenzaldehyde 
• 63909-51-3 2,5-Dimethylbenzylphosphonsaeurediethylester 
• 38489-74-6 trans-2,5-dimethoxycinnamic acid 
• 541-41-3 chloroformic acid ethyl ester 
• 140-88-5 ethyl acrylate 
• 150-78-7 1,4-dimethoxybezene 
• 64-17-5 ethanol 
• 117646-10-3 5-(2',5'-dimethoxybenzylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione 
• 109-63-7 boron trifluoride diethyl etherate 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 623-47-2 propynoic acid ethyl ester 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 10538-51-9 2,5-dimethoxycinnamic acid 

Downstream Products

• 72018-06-5 ethyl E-3-(2,5-dimethoxyphenyl)propanoate 
• 80152-61-0 2,2,6,6-tetramethyl-5-(2,5-dimethoxyphenyl)heptan-3-one 
• 80152-59-6 ethyl 4,4-dimethyl-3-(2,5-dimethoxyphenyl)pentanoate 
• 80152-60-9 ethyl 3,3-dimethyl-2-(2,5-dimethoxyphenylmethyl)butanoate 
• 56966-37-1 3-(2,5-dimethoxyphenyl)propan-1-amine 
• 33538-81-7 3-(2,5-Dimethoxyphenyl)propanol 
• 73126-26-8 1-benzyl-6-methoxy-1,2,3,4-tetrahydroquinoline 
• 936318-16-0 ethyl 2-(2,5-dimethoxybenzyl)pent-4-enoate 
• 936318-17-1 3-(2,5-dimethoxybenzyl)-2-methylhex-5-en-2-ol 
• 936318-18-2 4-(2,5-dimethoxybenzyl)-5,5-dimethyltetrahydrofuran-2-ol 
• 936318-19-3 4-(2,5-dimethoxybenzyl)-5,5-dimethyldihydro-2(3H)-furanone 

Relevant articles and documents

S,O-Ligand-Promoted Pd-Catalyzed C?H Olefination of Anisole Derivatives

The C?H olefination of substituted anisole derivatives by a Pd/S,O-ligand catalyst is reported. The reaction proceeds under mild conditions with a broad range of substituted aryl ethers bearing both electron donating and withdrawing substituents at ortho,

Controlling reactivity in the Fujiwara–Moritani reaction: Examining solvent effects and the addition of 1,3-dicarbonyl ligands on the oxidative coupling of electron rich arenes and acrylates

A palladium-catalysed direct alkenation of electron rich arenes in the presence of K2S2O8 with an acetic acid/1,4-dioxane solvent combination has been developed. The 1,4-dioxane co-solvent dramatically influences the rate of reaction, giving selectively disubstituted alkenes, while the addition of acetylacetone ligands was shown to increase site selectivity for the alkenation of monofunctionalized arenes. The participation of these carbonyl ligands has been confirmed by ESI-MS studies, with some key in situ intermediates in the catalytic cycle identified. A variety of electron rich arenes and olefinic substrates can be utilised in the direct oxidative coupling to give disubstituted alkenes in moderate to good yields.

Nucleophilic Amination of Methoxy Arenes Promoted by a Sodium Hydride/Iodide Composite

A method for the nucleophilic amination of methoxy arenes was established by using sodium hydride (NaH) in the presence of lithium iodide (LiI). This method offers an efficient route to benzannulated nitrogen heterocycles. Mechanistic studies showed that the reaction proceeds through an unusual concerted nucleophilic aromatic substitution.