1582301-19-6Relevant articles and documents
Manganese-mediated hydride delivery to a borazine by stepwise reduction and protonation
Carter, Tyler J.,Wang, Justin Y.,Szymczak, Nathaniel K.
, p. 1540 - 1543 (2014)
A Mn(CO)3+ fragment coordinates a borazine unit as a π complex, [(η6-Me6B3N 3)Mn(CO)3]BAr′. Coordination facilitates the delivery of alkyl and hydride nucleophiles, the latter of which can also be installed by successive reduction/protonation reactions. This system represents an alternative strategy to consider for the reduction of hydrogen depleted B-N molecules, which are relevant to the regeneration of spent B-N hydrogen storage systems.