15854-56-5

Basic information

• Product Name: 2-Propenoic acid, 3-(3-methoxyphenyl)-, methyl ester
• CAS NO: 15854-56-5
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 15854-56-5.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(3-methoxyphenyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(3-methoxyphenyl)-, methyl ester(15854-56-5)
• EPA Substance Registry System: 2-Propenoic acid, 3-(3-methoxyphenyl)-, methyl ester(15854-56-5)

Safety Data

• Hazardous Substances Data: 15854-56-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 26905-43-1 3-(3-methoxyphenyl)prop-2-en-1-ol 
• 591-31-1 3-methoxy-benzaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 96-32-2 bromoacetic acid methyl ester 
• 766-85-8 3-methoxy-1-iodobenzene 
• 292638-85-8 acrylic acid methyl ester 
• 2398-37-0 3-methoxyphenyl bromide 
• 14755-02-3 3-hydroxycinnamic acid 
• 74-88-4 methyl iodide 
• 6099-04-3 3-methoxycinnamic acid 

Downstream Products

• 68208-19-5 3-amino-3-(3-methoxy-phenyl)-propionic acid 
• 144878-41-1 1-(3,4-Dimethoxy-phenyl)-5,6-dimethoxy-3-methoxycarbonylmethyl-indan-2-carboxylic acid methyl ester 
• 141396-24-9 (1R,2S,3R,4S)-3,4-Bis-(3-methoxy-phenyl)-cyclobutane-1,2-dicarboxylic acid dimethyl ester 
• 6099-04-3 3-methoxycinnamic acid 
• 118510-03-5 methyl (E)-3-(3-methoxy-4-nitrophenyl)propenoate 

Relevant articles and documents

Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst

The direct esterification of alcohols with non-noble metal-based catalytic systems faces great challenges. Here, we report a new chrome-based catalyst stabilized by a single pentaerythritol decorated Anderson-type polyoxometalate, [N(C4H9)4]3[CrMo6O18(OH)3C{(OCH2)3CH2OH}], which can realize the efficient transformation from alcohols to esters by H2O2oxidation in good yields and high selectivity without extra organic ligands. A variety of alcohols with different functionalities including some natural products and pharmaceutical intermediates are tolerated in this system. The chrome-based catalyst can be recycled several times and still keep the original configuration and catalytic activity. We also propose a reasonable catalytic mechanism and prove the potential for industrial applications.

In situ synthesis of carbon nanotube-encapsulated cobalt nanoparticles by a novel and simple chemical treatment process: Efficient and green catalysts for the Heck reaction

In this study, we present a novel, fast and easy method for supporting metal nanoparticles onto the internal surface of multi-walled CNTs; these CNT-encapsulated nanoparticles as heterogeneous, efficient, inexpensive and green catalysts promote the Heck cross-coupling of a large library of functional substrates under mild and sustainable conditions. Remarkably, the introduced catalytic system could be reused for at least nine successive runs without a discernible decrease in its catalytic activity.

Fabrication of Pd/CuFe2O4 hybrid nanowires: A heterogeneous catalyst for Heck couplings

The development of environmentally benign transformations is indispensable in organic synthesis. Herein, a hybrid heterogeneous catalyst, palladium(0) on copper ferrite nanowires, has been synthesized, characterized, and for the first time, employed in the Jeffrey Heck reaction between iodoarenes and allylic alcohols, and good to excellent yields have been obtained. In addition, the catalyst was found to be suitable for the usual Heck coupling. The nanocatalyst was recovered and reused up-to multiple runs without any noticeable loss of its catalytic activity.