158727-08-3

Basic information

• Product Name: 1,5-Pentanediol, 1,1,5,5-tetraphenyl-
• CAS NO: 158727-08-3
• Molecular Formula: C29H28O2
• Molecular Weight: 408.54
• Mol File: 158727-08-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,5-Pentanediol, 1,1,5,5-tetraphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Pentanediol, 1,1,5,5-tetraphenyl-(158727-08-3)
• EPA Substance Registry System: 1,5-Pentanediol, 1,1,5,5-tetraphenyl-(158727-08-3)

Safety Data

• Hazardous Substances Data: 158727-08-3(Hazardous Substances Data)

Upstream product

• 1119-40-0 Dimethyl glutarate 
• 591-51-5 phenyllithium 
• 119-61-9 benzophenone 
• 28118-53-8 1,3-bis(phenylthio)propane 

Downstream Products

• 38503-54-7 1,1,5,5-Tetraphenyl-1,4-pentadiene 
• 158727-11-8 2,2,6,6-Tetraphenyl-tetrahydro-pyran 
• 858859-19-5 1,5-dimethoxy-1,1,5,5-tetraphenyl-pentane 
• 5271-41-0 1,1,5,5-tetraphenylpentane 
• 134643-56-4 Bis(4-ethoxycarbonyl-5-methyl-2,2-diphenyl-2,3-dihydro-3-furyl)methane 

Relevant articles and documents

1,3-bis(phenylmercapto)propane and 1-chloro-3-(phenylmercapto)propane: Useful precursors for 1,3-dilithiopropane synthons in the preparation of 1,5- diols

Treatment of 1,3-bis(phenylmercapto)propane (1) with an excess of lithium and a catalytic amount of DTBB (3.5 mol%) at -78°C followed by reaction with a carbonyl comPOund [BuCHO, PhCHO, (PhCH2)2CO, Et2CO, (CH2)7CO, [(CH2)7CO])-menthone, Ph2CO] leads, after hydrolysis with water, to symmetrically substituted 1,5-diols (2). Starting from 1-chloro-3- (phenylmercapto)propane (3) and by successive treatment with: (a) lithium- naphthalene at -78°C; (b) a carbonyl compound {Me2CO, (CH2)5CO, (CH2)7CO, (-)-menthone, [CH3(CH2)4]2CO] at the same temperature; (c) lithium powder at -50°C; and (d) a second carbonyl compound ['BuCHO, PhCHO] at the same temperature and final hydrolysis with water yields unsymmetrically substituted 1,5-diols (4). (C) 2000 Elsevier Science Ltd.