158749-41-8Relevant articles and documents
Effective chemiluminogenic systems based on acridinium esters bearing substituents of various electronic and steric properties
Zadykowicz, Beata,Czechowska, Justyna,Ozóg, Agnieszka,Renkevich, Anton,Krzymiński, Karol
, p. 652 - 668 (2015)
A series of 10-methyl-9-(phenoxycarbonyl)acridinium trifluoromethanesulfonates (XAEs), bearing substituents of various characteristics in the lateral benzene ring (2-halogen, 2,6-dihalogen, 2-trifluoromethyl, 2-nitro, 2-methoxy, 3-halogen and 4-halogen) w
Synthesis and properties of new luminescent 10-carboxymethylacridinium derivatives
Sato, Naofumi
, p. 8519 - 8522 (2007/10/03)
A novel method was developed to synthesize acridinium esters having a binding functional group at N-10. An acridine ester having steric hindrance is synthesized quickly, with excellent yields, using dimethylaminopyridine as a catalyst. Alkylation of the N-10 on the acridine ring proceeds using the trifluoromethanesulfonic acid ester under mild conditions. Deprotection of the benzyl ester using acid thus enables simple, high-yield synthesis for acridinium compounds with a binding functional group at N-10.