158785-74-1

Basic information

• Product Name: (4R,4'S,4''S)-2''-(Diphenyl-phosphinoylmethyl)-4,4',4''-trimethyl-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazole-4-carboxylic acid ethyl ester
• CAS NO: 158785-74-1
• Molecular Weight: 585.752
• Mol File: 158785-74-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,4'S,4''S)-2''-(Diphenyl-phosphinoylmethyl)-4,4',4''-trimethyl-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazole-4-carboxylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,4'S,4''S)-2''-(Diphenyl-phosphinoylmethyl)-4,4',4''-trimethyl-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazole-4-carboxylic acid ethyl ester(158785-74-1)
• EPA Substance Registry System: (4R,4'S,4''S)-2''-(Diphenyl-phosphinoylmethyl)-4,4',4''-trimethyl-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazole-4-carboxylic acid ethyl ester(158785-74-1)

Safety Data

• Hazardous Substances Data: 158785-74-1(Hazardous Substances Data)

Upstream product

• 158785-73-0 (4R,4'S)-2'-(Diphenyl-phosphinoylmethyl)-4,4'-dimethyl-4,5,4',5'-tetrahydro-[2,4']bithiazolyl-4-carboxylic acid ethyl ester 
• 158785-72-9 (R)-2-(Diphenyl-phosphinoylmethyl)-4-methyl-4,5-dihydro-thiazole-4-carboxylic acid ethyl ester 
• 158785-71-8 (R)-2-methylcysteine ethyl ester 
• 23040-22-4 (diphenylphosphoryl)acetonitrile 

Downstream Products

• 158785-75-2 (4R,4'S,4''S)-4,4',4''-Trimethyl-2''-((E)-styryl)-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazole-4-carboxylic acid ethyl ester 
• 138667-71-7 (-)-Thiangazole 
• 158785-76-3 (4R,4'S,4''S)-4,4',4''-Trimethyl-2''-((E)-styryl)-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazole-4-carboxylic acid amide 
• 257278-40-3 5-Methyl-2-[(4R,4'S,4''S)-4,4',4''-trimethyl-2''-((E)-styryl)-4,5,4',5',4'',5''-hexahydro-[2,4';2',4'']terthiazol-4-yl]-oxazole-4-carboxylic acid 

Relevant articles and documents

Natural Products as Pesticides: Two Examples of Stereoselective Synthesis

The strategy and synthetic efforts leading to efficient stereoselective syntheses of thiangazole, a tris-thiazolinyl-oxazole metabolite isolated from Polyangium spp., and hydantocidin, a spironucleoside metabolite isolated from Streptomyces hygroscopicus, are discussed.