158862-55-6Relevant articles and documents
A remarkable glycosylation reaction: The total synthesis of calicheamicin γ1I
Hitchcock, Stephen A.,Chu-Moyer, Margaret Y.,Boyer, Serge H.,Olson, Steven H.,Danishefsky, Samuel J.
, p. 5750 - 5756 (2007/10/02)
An account of the reasoning and reduction to practice of a highly convergent total stereospecific synthesis of calicheamicin y1I (1) is provided. The key finding was the use of a very mild promoter system (silver triflate and 4 ? mol