158870-93-0Relevant articles and documents
Retention of Configuration in the Ritter-type Substitution Reaction of Chiral β-Arylthio Alcohols through the Anchimeric Assistance of the Arylthio Group
Toshimitsu, Akio,Hirosawa, Chitaru,Tamao, Kohei
, p. 8997 - 9008 (2007/10/02)
In chiral alcohols bearing a phenylthio group at the β carbon atom, the hydroxy group is replaced by nitriles through the anchimeric assistance of the phenylthio group to afford chiral amides with retention of configuration.This stereospecific Ritter-type