159152-13-3Relevant articles and documents
Electrochemical Switching of a Fluorescent Molecular Rotor Embedded within a Bistable Rotaxane
Frasconi, Marco,Goddard, William A.,Liu, Wei-Guang,Stoddart, J. Fraser,Wasielewski, Michael R.,Wu, Yilei,Young, Ryan M.
, p. 11835 - 11846 (2020)
We report how the nanoconfined environment, introduced by the mechanical bonds within an electrochemically switchable bistable [2]rotaxane, controls the rotation of a fluorescent molecular rotor, namely, an 8-phenyl-substituted boron dipyrromethene (BODIP
Boron complexation strategy for use in manipulating 1-acyldipyrromethanes
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Page/Page column 16, (2008/06/13)
A method of making a metal complex comprises combining a 1-monoacyldipyrromethane with a compound of the formula R1R2MX, wherein M is boron, R1 and R2 are each independently organic substituents; and X is an anion leaving group; to produce a metal complex of the formula DMR1R2 wherein DH is a 1-monoacyldipyrromethane. The methods and complexes are useful for the purification and synthesis of dipyrromethanes and porphyrins.
Rational Synthesis of Trans-Substituted Porphyrin Building Blocks Containing One Sulfur or Oxygen Atom in Place of Nitrogen at a Designated Site
Cho, Won-Seob,Kim, Han-Je,Littler, Benjamin J.,Miller, Mark A.,Lee, Chang-Hee,Lindsey, Jonathan S.
, p. 7890 - 7901 (2007/10/03)
The use of heteroatom-substituted porphyrins in bioorganic and materials chemistry requires the ability to position a variety of substituents in a controlled manner about the porphyrin periphery. We describe a rational route to trans-AB2C-type
