159211-70-8Relevant articles and documents
New Access to Six-Membered Phosphacycle Annulated Polyaromatic Ring System
Si, Erbing,Zhao, Peng,Wang, Lili,Duan, Zheng,Mathey, Fran?ois
, p. 697 - 701 (2020)
A facile Ag-catalyzed intramolecular C–P bond formation reaction from easily accessible phosphine oxides has been developed. Several new heteroatoms fused π-conjugated molecules were synthesized from this procedure with their structures confirmed by X-ray
Cyclization of Bisphosphines to Phosphacycles via the Cleavage of Two Carbon-Phosphorus Bonds by Nickel Catalysis
Fujimoto, Hayato,Kusano, Momoka,Kodama, Takuya,Tobisu, Mamoru
supporting information, p. 4177 - 4181 (2019/06/17)
The nickel-catalyzed cyclization of bisphosphine derivatives to form various phosphacycles is reported. The reaction proceeds via the cleavage of two carbon-phosphorus bonds of the bisphosphine. Unlike the previously reported palladium catalysts, the use
Streoselective reaction of (+/-)-7-Phenyldinaphthophosphole with an optically active palladium complex. Molecular structure and fluxional behavior of PdCl
Tani, Kazuhide,Tashiro, Hironori,Yoshida, Miho,Yamagata, Tsuneaki
, p. 229 - 236 (2007/10/02)
Reaction of (+/-)-7-phenyldinaphthophosphole (1) with one-half equivalent of an optically active palladium complex, (μ-Cl)>2 ((S)-3a), proceeded stereoselectively to give one of the diastereomers, PdCl ((S)(P)-4a), accompanying racemization of 1.The X-ray crystallographic analysis of (S)(P)-4a determined the absolute configuration of the coordinated phosphole unequivocally to be P.The fluxional behavior of 4a and the related complex is also discussed.Key words: Palladium; Phosphine; Fluxionality; Isomerism; Stereoselectivity; X-ray diffraction
