159426-30-9Relevant articles and documents
Reactions of difluoroenoxysilanes with glycosyl donors: Synthesis of difluoro-C-glycosides and difluoro-C-disaccharides
Berber, Hatice,Brigaud, Thierry,Lefebvre, Olivier,Plantier-Royon, Richard,Portella, Charles
, p. 903 - 909 (2007/10/03)
Difluoroenoxysilanes, prepared from acylsilanes and trifluoromethyltrimethylsilane under fluoride activation, were glycosylated with some glycosyl donors (acylglycosides, glycals) to yield difluoro-C-glycosides with a difluoromethylene group in the place
Preparation of 2,2-difluoroenol silyl ethers by electroreductive defluorination of trifluoromethyl ketones
Uneyama, Kenji,Maeda, Kazushige,Kato, Tsuyoshi,Katagiri, Toshimasa
, p. 3741 - 3744 (2007/10/03)
2,2-Difluoroenol silyl ethers (5) were prepared by electroreductive defluorination of trifluoromethyl ketones (4) in the presence of chlorotrialsilanes (TMSCl, TESCl, TBDMSCl).