1595-04-6Relevant articles and documents
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Merrill,R.E.,Negishi,E.
, p. 3452 - 3453 (1974)
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Alkylation-Terminated Catellani Reactions Using Alkyl Carbagermatranes
Jiang, Wei-Tao,Xiao, Bin,Xie, Xiu-Ying,Xu, Meng-Yu,Yang, Shuo
supporting information, p. 20450 - 20454 (2020/09/07)
The Catellani reaction has received substantial attention because it enables rapid multiple derivatization on aromatics. While using alkyl electrophiles to achieve ortho-alkylation was one of the earliest applications of the Catellani reaction, ipso-alkyl
Reductive activation of arenes 21. Reaction of products of two-electron reduction of arenecarbonitriles by alkali metals in liquid ammonia with bromo-and dibromoalkanes
Vaganova,Panteleeva,Yuferov,Rebitva,Shteingarts
, p. 981 - 986 (2008/02/01)
Reductive alkylation of benzonitrile, ortho-, meta-, para-tolunitriles, and 1-naphthonitrile by sequential action of alkali metal and alkyl bromide in liquid ammonia results in corresponding alkylarenes and 1-alkyl-1- cyanocyclohexa-2,5-dienes. The experimental conditions for target synthesis of the specified products are found. A method of synthesis of 1-(ω- bromoalkyl)-1-cyanocyclohexa-2,5-dienes based on the interaction of two-electronic reduction products of aromatic nitriles with α,ω- dibromoalkanes Br(CH2)nBr (n = 3-5) is developed.
Reductive activation of arenes: XVII. Effect of methyl substituent in anion-radicals of tolunitriles on the mechanism of their reaction with alkyl bromides in liquid ammonia
Vaganova,Shteingarts
, p. 747 - 750 (2007/10/03)
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