1596361-49-7Relevant articles and documents
Cleavage of C-C and C-Si σ-bonds and their intramolecular exchange
Ishida, Naoki,Ikemoto, Wataru,Murakami, Masahiro
supporting information, p. 5912 - 5915 (2014/05/20)
C-C and C-Si σ-bonds are cleaved to undergo bond exchange when substrates equipped with cyclobutanone and silacyclobutane moieties are treated with a palladium(0) catalyst. The skeletal exchange results in construction of silabicyclo[5.2.1]decanes in a diastereoselective manner.