15965-42-1

Basic information

• Product Name: 1,4,2-Dithiazole-5-thione, 3-(4-methoxyphenyl)-
• CAS NO: 15965-42-1
• Molecular Formula: C9H7NOS3
• Molecular Weight: 241.359
• Mol File: 15965-42-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,4,2-Dithiazole-5-thione, 3-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4,2-Dithiazole-5-thione, 3-(4-methoxyphenyl)-(15965-42-1)
• EPA Substance Registry System: 1,4,2-Dithiazole-5-thione, 3-(4-methoxyphenyl)-(15965-42-1)

Safety Data

• Hazardous Substances Data: 15965-42-1(Hazardous Substances Data)

Upstream product

• 2362-64-3 p-methoxythiobenzamide 
• 594-42-3 chlorothio-trichloro-methane 

Downstream Products

• 15965-48-7 8-(4-methoxy-phenyl)-3-phenyl-1-oxa-4,6,9-trithia-2,7-diaza-spiro[4.4]nona-2,7-diene 
• 15965-45-4 3-(4-methoxy-phenyl)-[1,4,2]dithiazol-5-one 
• 98711-41-2 3-ethoxycarbonyl-1,4,2-dithiazole-5-thione 
• 874-90-8 4-methoxybenzonitrile 
• 59291-73-5 dimethyl 3-(p-methoxyphenyl)isothiazole-4,5-dicarboxylate 

Relevant articles and documents

Cycloaddition Reaction of 1,4,2-Dithiazole-5-thiones

1,4,2-Dithiazole-5-thiones can act either as the 2-atom or the 3-atom component in 2+3-cycloadditions.Benzonitrile N-phenylimine, generated in situ by dehydrochlorination of N-phenylbenzohydrazonoyl chloride, reacts at the exocyclic C=S double bond forming the thiadiazolethione (17) and the spiro compound (18) by collapse of the initial cycloadduct (19) and further 1,3-dipolar cycloaddition.The corresponding reaction with ethyl azidoformate yields a 5-ethoxycarbonylimino-1,4,2-dithiazole.On treatment-with dimethyl acetylenedicarboxylate and ethylcyanoformate the dithiazolethione itself acts as a 1,3-dipole forming 1,3-dithiole and 1,4,2-dithiazolethiones with expulsion of a nitrile fragment.