1598412-40-8

Basic information

• Product Name: 1,3-dibromo-5-(4-trifluoromethylphenyl)thieno[3,4-c]pyrrole-4,6-dione
• Synonyms: 1,3-dibromo-5-(4-trifluoromethylphenyl)thieno[3,4-c]pyrrole-4,6-dione
• CAS NO: 1598412-40-8
• Molecular Weight: 455.049
• Mol File: 1598412-40-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-dibromo-5-(4-trifluoromethylphenyl)thieno[3,4-c]pyrrole-4,6-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-dibromo-5-(4-trifluoromethylphenyl)thieno[3,4-c]pyrrole-4,6-dione(1598412-40-8)
• EPA Substance Registry System: 1,3-dibromo-5-(4-trifluoromethylphenyl)thieno[3,4-c]pyrrole-4,6-dione(1598412-40-8)

Safety Data

• Hazardous Substances Data: 1598412-40-8(Hazardous Substances Data)

Upstream product

• 1598412-41-9 C₁₃H₆Br₂F₃NO₃S 
• 1015423-45-6 2,5-dibromothiophene-3,4-dicarboxylic acid anhydryde 

Relevant articles and documents

Fine tuning of frontier orbital energy levels in dithieno[3,2-b:2′, 3′-d]silole-based copolymers based on the substituent effect of phenyl pendants

A series of dithieno[3,2-b:2′,3′-d]silole-based π-conjugated copolymers containing thieno[3,4-c]pyrrole-4,6-dione or thieno[3,4-b]thiophene units bearing 4-substituted phenyl pendants were synthesized and their thermal stability, optical properties and frontier orbital energy levels were systematically investigated. The introduction of electron-withdrawing substituents on the phenyl rings lowered their frontier orbital energy levels without deteriorating their thermal and optical properties. By replacing an electron-donating methoxy group with an electron-withdrawing trifluoromethyl group, both the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital energy levels of the polymers were deepened by more than 0.3 eV. A relatively linear relationship was observed between the HOMO energy levels and the Hammett substituent constants.