1601-94-1

Basic information

• Product Name: (R)-1-(1-phenylethylsulfonyl)benzene
• Synonyms: (R)-1-(1-phenylethylsulfonyl)benzene
• CAS NO: 1601-94-1
• Molecular Weight: 246.33
• Mol File: 1601-94-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-1-(1-phenylethylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-(1-phenylethylsulfonyl)benzene(1601-94-1)
• EPA Substance Registry System: (R)-1-(1-phenylethylsulfonyl)benzene(1601-94-1)

Safety Data

• Hazardous Substances Data: 1601-94-1(Hazardous Substances Data)

Upstream product

• 40390-78-1 [(1-phenylethyl)thio]benzene 
• 65588-57-0 C₂₂H₂₃NO₄S₂ 
• 882-33-7 diphenyldisulfane 
• 22852-28-4 (((R_S,R_C)-1-phenylethyl)sulfinyl)benzene 
• 98-59-9 p-toluenesulfonyl chloride 
• 17279-31-1 (-)-(S)-N,N-dimethyl-1-phenylethylamine 
• 873-55-2 sodium benzenesulfonate 
• 51262-06-7 (-)-menthyl (S)-benzenesulfinate 
• 60779-09-1 1-phenylethylmagnesium chloride 

Relevant articles and documents

17O NMR Spectra of Tertiary Alcohols, Ethers, Sulfoxides and Sulfones in the Cyclohexyl and 5-Substituted 1,3-Dioxanyl Series and Related Compounds

17O NMR spectra of fifteen cyclohexane-derived tertiary alcohols and related ethers and acetals, six 1,3-dioxane-derived orthoesters, four cyclohexane- and 1,3-dioxane-derived sulfones and the four corresponding sulfoxides, three acyclic sulfones, six alc

Cu2O-catalyzed C–S coupling of quaternary ammonium salts and sodium alkane-/arene-sulfinates

A new protocol for the synthesis of (enantioenriched) benzylic sulfones via the Cu2O-catalyzed C–S bond cross coupling of alkane-/arene-sulfinates and (enantioenriched) benzylic quaternary ammonium salts has been developed. The product benzylic sulfones were obtained in good to high yields (75–96%). Chiral arylmethyl sulfones with high enantiomeric excess (90–94% ee) were also synthesized in the presence of Cu2O and 1,1′-bis-(diphenylphosphino)ferrocene (dppf).