160154-68-7Relevant articles and documents
Binucleating ligands: Synthesis of acyclic achiral and chiral Schiff base-pyridine and Schiff base-phosphine ligands
Lam, Fung,Xu, Jia Xi,Chan, Kin Shing
, p. 8414 - 8418 (1996)
5-tert-Butyl-3-(2′-pyridyl)salicyaldehyde and 5-tert-butyl-3-(diphenylphosphino)salicyaldehyde were synthesized from 4-tert-butylphenol in good overall yields. Condensation of the salicyaldehydes with 2,3-diamino-2,3-dimethylbutane afforded the desired dinucleating Schiff base-pyridine and Schiff base-phosphine ligands, respectively. 5-tert-Butyl-3-(2′-pyridyl)salicyaldehyde reacted with optically active 1,2-diaminocyclohexanes to give chiral dinucleating Schiff base-pyridine ligands.
Synthesis of acyclic dinucleating Schiff base-pyridine and Schiff base-phosphine ligands
Lam, Fung,Chan, Kin Shing
, p. 919 - 922 (2007/10/02)
5-tert-butyl-3-pyridyl-salicyaldehyde and 5-tert-butyl-3-diphenylphosphino-salicyaldehyde have been synthesized from 4-tert-butylphenol in good overall yields. Condensation of the salicyaldehydes with 2,3-diamino-2,3-dimethylbutane afforded the desired dinucleating Schiff base-pyridine and Schiff base-phosphine ligands respectively.