160196-16-7Relevant articles and documents
Reaction of 1,6-dioxo-2,4-diene with aziridine and secondary amine
Sun, Tsung-Hsien,Ong, Chi-Wi
, p. 1595 - 1600 (2007)
The (2E,4E)- and (2E,4Z)-1-phenyl-1,6-dioxo-hepta-2,4-diene reacts with aziridine to give aziridinecyclopentenol 3. This product arises from an intermolecular Michael addition of a nitrogen lone pair to the less reactive enone, followed by an intramolecul
Convenient synthesis of 2,5-disubstituted thiophene from 1,6-dioxo-2,4- diene
Ong, Chi Wi,Chen, Chong Ming,Wang, Long Fu,Shieh, Po Chuen
, p. 9191 - 9192 (2007/10/03)
Reaction of 1,6-dioxo-2,4-diene with P2S5 and Lawesson's reagent affords the 2,5-disubstituted thiophene. This reaction can take place regioselectively in the presence of BF3-etherate catalysis, useful for the synthesis of