160771-25-5Relevant articles and documents
Synthesis of 1-Arylacenaphthopyrazoles and 5,7-Dehydro-5H,7H-benzoacenaphtho-1,3a,6a-triazapentalenes
Tsuge, Otohiko,Hatta, Taizo,Kojima, Hisashi,Miyahara, Nobutaka,Sugaya, Masafumi
, p. 1283 - 1288 (2007/10/02)
2-Benzoyl- 5 and 2-acetylacenaphthenone 6, prepared from the corresponding 1-acyl-2-(1-pyrrolidinyl)-acenaphthylenes 2 and 3, reacted with arylhydrazines 8 under acidic conditions to give the corresponding 1-arylacenaphthopyrazoles 9 and 10.Novel heteropentalene mesomeric betaines, 5,7-dehydro-5H,7H-benzoacenaphtho-1,3a,6a-triazapentalenes 13 and 14 were prepared by reductive cyclization of 1-(o-nitrophenyl)acenaphthopyrazoles 9d and 10d, respectively.