16078-91-4Relevant articles and documents
Photo-crosslinkable second order nonlinear AB2-type monomers: Convenient synthesis and enhanced NLO thermostability
Cheng, Ziyao,Deng, Xiaocong,Li, Qianqian,Li, Zhen,Wang, Ruifang,Zhao, Wenjing
supporting information, p. 6380 - 6387 (2020/06/09)
In this article, two AB2-type second-order nonlinear optical monomers (DN-SH and DS-SH) containing two double bonds and one thiol group, respectively, were synthesized successfully. These two monomers could be in situ photo-crosslinked via a th
Copper-Catalyzed Dicarbofunctionalization of Unactivated Olefins by Tandem Cyclization/Cross-Coupling
Thapa, Surendra,Basnet, Prakash,Giri, Ramesh
supporting information, p. 5700 - 5703 (2017/05/04)
We present a strategy that difunctionalizes unactivated olefins in 1,2-positions with two carbon-based entities. This method utilizes alkyl/arylzinc reagents derived from olefin-tethered alkyl/aryl halides that undergo radical cyclization to generate C(sp3)-Cu complexes in situ, which are intercepted with aryl and heteroaryl iodides. A variety of (arylmethyl)carbo- and heterocycles (N, O) can be synthesized with this new method.
One-Pot Synthesis of O-Allylhydroxylamines through the Organocatalytic Oxidation of Tertiary Allylic Amines Followed by a [2,3]-Meisenheimer Rearrangement
Theodorou, Alexis,Limnios, Dimitris,Kokotos, Christoforos G.
supporting information, p. 5238 - 5241 (2015/03/30)
A cheap, green, and highly efficient one-pot method for the synthesis of O-protected allylic alcohols is described. By utilizing 2,2,2-trifluoroacetophenone as the organocatalyst and H2O2 as the oxidant, a variety of allylic amine N-
