16081-16-6

Basic information

• Product Name: Phenol, 2,6-dimethyl-, sodium salt
• CAS NO: 16081-16-6
• Molecular Formula: C8H10O.Na
• Molecular Weight: 144.149
• Mol File: 16081-16-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Phenol, 2,6-dimethyl-, sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,6-dimethyl-, sodium salt(16081-16-6)
• EPA Substance Registry System: Phenol, 2,6-dimethyl-, sodium salt(16081-16-6)

Safety Data

• Hazardous Substances Data: 16081-16-6(Hazardous Substances Data)

Upstream product

• 576-26-1 2.6-dimethylphenol 
• 108-89-4 picoline 

Downstream Products

• 124377-60-2 2-(2,6-dimethyl-phenoxy)-propionic acid 
• 59516-91-5 γ,γ-Dimethylallyl-(2,6-dimethylphenyl)-ether 
• 123557-95-9 methyl α-(4-hydroxy-3,5-dimethylphenyl)-α-hydroxy-β,β,β-trifluoropropionate 
• 4919-37-3 3,5-dimethyl-4-hydroxybenzoic acid 
• 22040-02-4 1,3-dimethyl-2-phenoxybenzene 
• 126075-59-0 (2,6-Me₂-C₆H₃O)Cl₂(tetrahydrofuran)2 vanadium(III) 
• 438247-29-1 C₆H₃(CH₃)2ONiCH₃(P(CH₃)3)2 
• 859507-23-6 [Zr(N,N-di(pyrrolyl-α-methyl)-N-methylamine)(2,6-dimethylphenolate)3Na(4,4'-di-tert-butyl-2,2'-bipyridine)] 
• 1141898-48-7 Sn(2,6-dimethylphenoxide)4 
• 6279-47-6 ethyl 2-(2,6-dimethylphenoxy)acetate 
• 29768-35-2 Carbonimidsaeurebis(2,6-dimethylphenylester) 
• 2950-32-5 4-(2-hydroxyhexafluoroisopropyl)-2,6-dimethylphenol 
• 142619-41-8 2,2,4,4,6,6-Hexakis-(2,6-dimethyl-phenoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine 
• 142619-40-7 2,2,4,4-Tetrachloro-6,6-bis-(2,6-dimethyl-phenoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinine 

Relevant articles and documents

Highly active chromium-based selective ethylene tri-/tetramerization catalysts supported by PNPO phosphazane ligands

Novel Cr(iii) catalysts supported by PNPO phosphazane ligands of the type Ph2PN(R)P(Ph)OAr have been prepared, all of which, upon activation with MMAO-3A, are highly active in ethylene tri-/tetramerization with considerable selectivity. The effect of ligand substitution on the catalytic performance has been examined. The Cr precatalyst supported by the PNPO phosphazane ligand with an N-cyclohexyl achieved high activity of 316.7 kg (g Cr h-1)-1 and a high total selectivity of 85.1% towards valuable 1-hexene (45.7%) and 1-octene (39.4%) using chlorobenzene as the solvent at 35 bar and 40 °C. In methylcyclohexane, the precatalyst supported by [Ph2PN(iPr)P(Ph)OPh] exhibited a higher 1-octene selectivity (54.0%) with a considerable activity of 73.3 kg (g Cr h-1)-1 at 35 bar and 40°C. With the fine-tuned ligand backbone, such a PNPO phosphazane-based catalyst system provides a mode for precise understanding of the impact of ligand variations on catalytic performance.

Aryloxymethyl derivatives of nitrogenous heterocyclic methanols and ethers thereof

Novel heterocyclicmethanols are disclosed having the formula: STR1 wherein Z is pyrrolidinyl, piperidinyl, homopiperidinyl or pyridinyl; R1 is hydrogen, loweralkyl or carbethoxymethyl; R2 is hydrogen, loweralkyl, cycloalkyl, phenyl or phenyl-loweralkyl; R3 is 1 or 2-naphthalenyl, 2,3-dihydroinden-4 or 5-yl, phenyl or phenyl substituted by loweralkyl, loweralkoxy, halogen, trifluoromethyl, phenyl, methylenedioxy, nitro, amino, loweralkylamino, diloweralkylamino, loweracylamino; the 1-position of 2-pyrrolidinyl, 2-piperidinyl or 2-homopiperidinyl may be substituted by an R4 loweralkyl group, or R1 may form methylene or --CH2 -C(O)-bridges with R4 ; the pharmaceutically acceptable salts and diastereomers thereof, which compounds have antiarrhythmic and/or hypotensive activity in animals.

Process for the preparation of alkylthioalkanoate salts

A process for the preparation of alkylthioalkanoate salts by reaction of an alkali metal alkylmercaptide with a lactone in the presence of an aprotic polar organic solvent. Preferably, the alkali metal mercaptide is prepared by reaction of an alkylmercaptan and an alkali metal phenate.