1610803-43-4

Basic information

• Product Name: C₃₈H₃₀ClCoN₂S₂
• CAS NO: 1610803-43-4
• Molecular Weight: 673.248
• Mol File: 1610803-43-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₈H₃₀ClCoN₂S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₃₀ClCoN₂S₂(1610803-43-4)
• EPA Substance Registry System: C₃₈H₃₀ClCoN₂S₂(1610803-43-4)

Safety Data

• Hazardous Substances Data: 1610803-43-4(Hazardous Substances Data)

Upstream product

• 1404065-91-3 C₃₈H₃₀N₂S₂^(2-)*Co⁽²⁺⁾ 
• 56-34-8 tetraethylammonium chloride 

Relevant articles and documents

A bio-inspired switch based on cobalt(II) disulfide/cobalt(III) thiolate interconversion

Disulfide/thiolate interconversion supported by transition-metal ions is proposed to be implicated in fundamental biological processes, such as the transport of metal ions or the regulation of the production of reactive oxygen species. We report herein a mononuclear dithiolate CoIII complex, [CoIIILS(Cl)] (1; LS=sulfur containing ligand), that undergoes a clean, fast, quantitative and reversible CoII disulfide/Co III thiolate interconversion mediated by a chloride anion. The removal of Cl- from the CoIII complex leads to the formation of a bis(μ-thiolato) μ-disulfido dicobalt(II) complex, [Co 2II,IILSSL]2+ (22+). The structures of both complexes have been resolved by single-crystal X-ray diffraction; their magnetic, spectroscopic, and redox properties investigated together with DFT calculations. This system is a unique example of metal-based switchable M n2-RSSR/2 M(n+1)-SR (M=metal ion, n=oxidation state) system that does not contain copper, acts under aerobic conditions, and involves systems with different nuclearities. A switchable CoII 2 disulfide/CoIII thiolate system (see scheme; filled circles show the color change) is stable under aerobic conditions. It offers the chance to understand the disulfide/thiolate interconversion supported by transition-metal ions, which is proposed to be involved in various fundamental biological processes.