1612246-09-9

Basic information

• Product Name: (Z)-2-(1-(4-chlorophenyl)-5-phenylpent-2-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: (Z)-2-(1-(4-chlorophenyl)-5-phenylpent-2-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1612246-09-9
• Molecular Weight: 382.738
• Mol File: 1612246-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-2-(1-(4-chlorophenyl)-5-phenylpent-2-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-(1-(4-chlorophenyl)-5-phenylpent-2-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1612246-09-9)
• EPA Substance Registry System: (Z)-2-(1-(4-chlorophenyl)-5-phenylpent-2-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1612246-09-9)

Safety Data

• Hazardous Substances Data: 1612246-09-9(Hazardous Substances Data)

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 40339-21-7 penta-3,4-dienyl-benzene 
• 73183-34-3 bis(pinacol)diborane 

Relevant articles and documents

Copper-catalyzed cross-coupling of boronic esters with aryl iodides and application to the carboboration of alkynes and allenes

Copper-catalyzed Suzuki-Miyaura-type cross-coupling and carboboration processes are reported. The cross-couplings function well with a variety of substituted aryl iodides and aryl boronic esters and allows for orthogonal reactivity compared to palladium-catalyzed processes. The carboboration method includes both alkynes and allenes and provides access to highly substituted and stereodefined vinyl boronic esters. The alkyne carboboration method is highlighted in the simple one-pot synthesis of Tamoxifen. Cross-Cu-pling: The title cross-couplings function well with a variety of substituted aryl iodides and aryl boronic esters and allows for reactivity orthogonal to that of the palladium-catalyzed processes. The title carboboration method includes both alkynes and allenes and provides access to highly substituted and stereodefined vinyl boronic esters. The alkyne carboboration method is highlighted in a simple one-pot synthesis of Tamoxifen.