1613249-88-9

Basic information

• Product Name: C₁₇H₂₂O₂
• CAS NO: 1613249-88-9
• Molecular Weight: 258.36
• Mol File: 1613249-88-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₂₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₂₂O₂(1613249-88-9)
• EPA Substance Registry System: C₁₇H₂₂O₂(1613249-88-9)

Safety Data

• Hazardous Substances Data: 1613249-88-9(Hazardous Substances Data)

Upstream product

• 2177-32-4 vinyl isobutyl ketone 
• 495-41-0 1-phenylbut-2-en-1-one 

Relevant articles and documents

A dual-catalysis approach to enantioselective [2 + 2] photocycloadditions using visible light

In contrast to the wealth of catalytic systems that are available to control the stereochemistry of thermally promoted cycloadditions, few similarly effective methods exist for the stereocontrol of photochemical cycloadditions. A major unsolved challenge in the design of enantioselective catalytic photocycloaddition reactions has been the difficulty of controlling racemic background reactions that occur by direct photoexcitation of substrates while unbound to catalyst. Here, we describe a strategy for eliminating the racemic background reaction in asymmetric [2 + 2] photocycloadditions of a,b-unsaturated ketones to the corresponding cyclobutanes by using a dual-catalyst system consisting of a visible light-absorbing transition-metal photocatalyst and a stereocontrolling Lewis acid cocatalyst. The independence of these two catalysts enables broader scope, greater stereochemical flexibility, and better efficiency than previously reported methods for enantioselective photochemical cycloadditions.