1613527-37-9Relevant articles and documents
Highly enantioselective synthesis of chiral cyclic allylic amines via RH-catalyzed asymmetric hydrogenation
Zhou, Ming,Liu, Tang-Lin,Cao, Min,Xue, Zejian,Lv, Hui,Zhang, Xumu
supporting information, p. 3484 - 3487 (2014/07/21)
Highly regioselective and enantioselective asymmetric hydrogenation of cyclic dienamides catalyzed by an Rh-DuanPhos complex has been developed, which provides a readily accessible method for the synthesis of chiral cyclic allylic amines in excellent enantioselectivities (up to 99% ee). The products are valuable chiral building blocks and could be easily transformed to multisubstituted cyclohexane derivatives.