16149-84-1

Basic information

• Product Name: 1-Oxaspiro[4.5]decan-2-one, 3-methyl-
• CAS NO: 16149-84-1
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol File: 16149-84-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Oxaspiro[4.5]decan-2-one, 3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Oxaspiro[4.5]decan-2-one, 3-methyl-(16149-84-1)
• EPA Substance Registry System: 1-Oxaspiro[4.5]decan-2-one, 3-methyl-(16149-84-1)

Safety Data

• Hazardous Substances Data: 16149-84-1(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 6244-44-6 trans-1-(1-propenyl)cyclohexanol 
• 1123-34-8 1-allyl-1-cyclohexanol 

Relevant articles and documents

A new synthesis of lactones from tertiary alkenylcarbinols by cobalt-catalyzed photocarbonylation under ambient conditions

In the presence of a Co catalyst, tertiary vinyl-, propenyl-, and allylcarbinols were chelatively cycloadded to carbon monoxide to produce lactones by xanthone-sensitized photoreaction in tetrahydrofuran, under CO at 1 atmosphere and at room temperature.At lower temperatures the isomerization of alkenyl-carbinols was suppressed and lactones were obtained with improved selectivity.The photoprocess was facilitated by addition of pyridine or hydrogen and retarded in presence of amines or phosphines.Mechanistic interpretations for the process and the accompanying effects are discussed.Key words: chelative carbonylation, photocarbonylation, carbonylation of olefins, lactones synthesis from alkenylalcohols.