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1616799-23-5

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1616799-23-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1616799-23-5 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,6,1,6,7,9 and 9 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1616799-23:
(9*1)+(8*6)+(7*1)+(6*6)+(5*7)+(4*9)+(3*9)+(2*2)+(1*3)=205
205 % 10 = 5
So 1616799-23-5 is a valid CAS Registry Number.

1616799-23-5Downstream Products

1616799-23-5Relevant articles and documents

Photoinduced Nickel-Catalyzed Chemo- and Regioselective Hydroalkylation of Internal Alkynes with Ether and Amide α-Hetero C(sp3)-H Bonds

Deng, Hong-Ping,Fan, Xuan-Zi,Chen, Zhi-Hui,Xu, Qing-Hua,Wu, Jie

, p. 13579 - 13584 (2017/10/05)

A direct hydroalkylation of disubstituted alkynes with unfunctionalized ethers and amides was achieved in an atom-efficient and additive-free manner through the synergistic combination of photoredox and nickel catalysis. The protocol was effective with a wide range of internal alkynes, providing products in a highly selective fashion. Notably, the observed regioselectivity is complementary to conventional radical addition processes. Mechanistic investigations suggest that the photoexcited iridium catalyst facilitated the nickel activation via single-electron transfer.

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