1616860-66-2

Basic information

• Product Name: 2,3-bis((E)-(3,5-di-tert-butyl-2-hydroxybenzylidene)amino)propan-1-ol
• Synonyms: 2,3-bis((E)-(3,5-di-tert-butyl-2-hydroxybenzylidene)amino)propan-1-ol
• CAS NO: 1616860-66-2
• Molecular Weight: 522.772
• Mol File: 1616860-66-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-bis((E)-(3,5-di-tert-butyl-2-hydroxybenzylidene)amino)propan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-bis((E)-(3,5-di-tert-butyl-2-hydroxybenzylidene)amino)propan-1-ol(1616860-66-2)
• EPA Substance Registry System: 2,3-bis((E)-(3,5-di-tert-butyl-2-hydroxybenzylidene)amino)propan-1-ol(1616860-66-2)

Safety Data

• Hazardous Substances Data: 1616860-66-2(Hazardous Substances Data)

Upstream product

• 2811-20-3 N-(1-aminomethyl-2-hydroxyethyl)amine 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 

Downstream Products

• 1616860-68-4 2,3-bis((E)-(3,5-di-tert-butyl-2-hydroxybenzylidene)amino)propyl methanesulfonate 

Relevant articles and documents

Steric effects in the design of Co-Schiff base complexes for the catalytic oxidation of lignin models to para-benzoquinones

New Co-Schiff base complexes that incorporate a sterically hindered ligand and an intramolecular bulky piperazine base in close proximity to the Co center are synthesized. Their utility as catalysts for the oxidation of para-substituted lignin model phenols with molecular oxygen is examined. Syringyl and guaiacyl alcohol, as models of S and G units in lignin, are oxidized in good yield using a catalyst bearing an N-benzylpiperazinyl substituent, with the catalysts displaying improved reactivity for G oxidation. Computational evaluation of the catalysts shows that the piperazinyl substituent is within bonding distance of the Co center. The increased steric interference is suggested as the source of increased G reactivity. This journal is the Partner Organisations 2014.