1617001-65-6

Basic information

• Product Name: [Rh(5,10,15,20-tetraphenylporphyrinato)(n-octyl)]
• Synonyms: [Rh(5,10,15,20-tetraphenylporphyrinato)(n-octyl)]
• CAS NO: 1617001-65-6
• Molecular Weight: 828.862
• Mol File: 1617001-65-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(5,10,15,20-tetraphenylporphyrinato)(n-octyl)](CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(5,10,15,20-tetraphenylporphyrinato)(n-octyl)](1617001-65-6)
• EPA Substance Registry System: [Rh(5,10,15,20-tetraphenylporphyrinato)(n-octyl)](1617001-65-6)

Safety Data

• Hazardous Substances Data: 1617001-65-6(Hazardous Substances Data)

Upstream product

• 69509-35-9 RhI(tetraphenylporphyrin) 
• 14866-33-2 tetraoctyl ammonium bromide 

Relevant articles and documents

Alkylation of rhodium porphyrins using ammonium and quinolinium salts

Alkylation of rhodium(III) porphyrins [RhIII(por)] was achieved under relatively mild conditions in up to 98% yields, where readily available ammonium and quinolinium salts were utilized as the alkylating agents. This transformation tolerates air and water, thus serving as a convenient method to prepare a variety of alkyl- and benzyl-RhIII(por) complexes. Preliminary mechanistic studies support an SN2-like reaction pathway involving a RhI(por) anion intermediate.