1618666-64-0Relevant articles and documents
Palladium-catalyzed/norbornene-mediated ortho-amination/N-tosylhydrazone insertion reaction: An approach to the synthesis of ortho-aminated vinylarenes
Zhou, Ping-Xin,Ye, Yu-Ying,Ma, Jun-Wei,Zheng, Lan,Tang, Qian,Qiu, Yi-Feng,Song, Bo,Qiu, Zi-Hang,Xu, Peng-Fei,Liang, Yong-Min
, p. 6627 - 6633 (2014/08/05)
ortho-Aminated vinylarene derivatives were obtained via a reaction of aryl iodides, N-benzoyloxyamines, and N-tosylhydrazones. This approach involves a palladium-catalyzed, norbornene-mediated ortho-amination/N-tosylhydrazone insertion reaction. In this transformation, one C-N bond and one C-C bond are formed and an amine group is introduced at the ortho position successfully.