161925-56-0

Basic information

• Product Name: methyl (3R,5S)-5-phenyl-4-benzyl-3-<4-(tert-butyldimethylsiloxy)phenyl>-4-azahexanoate
• Synonyms: methyl (3R,5S)-5-phenyl-4-benzyl-3-<4-(tert-butyldimethylsiloxy)phenyl>-4-azahexanoate
• CAS NO: 161925-56-0
• Molecular Weight: 503.757
• Mol File: 161925-56-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (3R,5S)-5-phenyl-4-benzyl-3-<4-(tert-butyldimethylsiloxy)phenyl>-4-azahexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (3R,5S)-5-phenyl-4-benzyl-3-<4-(tert-butyldimethylsiloxy)phenyl>-4-azahexanoate(161925-56-0)
• EPA Substance Registry System: methyl (3R,5S)-5-phenyl-4-benzyl-3-<4-(tert-butyldimethylsiloxy)phenyl>-4-azahexanoate(161925-56-0)

Safety Data

• Hazardous Substances Data: 161925-56-0(Hazardous Substances Data)

Upstream product

• 17480-69-2 (S)-N-benzyl-1-phenylethylamine 
• 426207-35-4 (E)-methyl 3-(4-(tert-butyldimethylsilyloxy)phenyl)acrylate 
• 3943-97-3 methyl 4-hydroxycinnamate 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 161925-58-2 methyl (3R,6R,9S,12S,14E,16R,18S)-6-<(2-bromo-1H-indol-3-yl)methyl>-18-benzoyloxy-3-<4-(tert-butyldimethylsilyloxy)phenyl>-7,9,12,14,16-pentamethyl-5,8,11-trioxo-4,7,10-triazanonadeca-14-enoate 
• 161925-57-1 methyl (3R,6R,9S)-9-(tert-butoxycarbonylamino)-7-methyl-6-<(2-bromo-1H-indol-3-yl)methyl>-3-<4-(tert-butyldimethylsilyloxy)phenyl>-5,8-dioxo-4,7-diazadecanoate 
• 161925-44-6 methyl (3R,6R,9S)-9-amino-7-methyl-6-<(2-bromo-1H-indol-3-yl)methyl>-3-<4-(tert-butyldimethylsilyloxy)phenyl>-5,8-dioxo-4,7-diazadecanoate 
• 161925-59-3 jaspamide Z₁ 
• 119717-37-2 jasplakinolide 
• 161925-45-7 methyl (R)-3-amino-3-<4-(tert-butyldimethylsiloxy)phenyl>propanoate 

Relevant articles and documents

A synthesis of Jaspamide based on 1,2-metallate rearrangements of α-heteroalkenylmetal derivatives

Jaspamide (Jasplakinolide), a marine cyclodepsipeptide, was synthesised from tripeptide fragment 4 and (2S,4E,6R,8S)-8-benzoyloxy-2,4,6-trimethylnon-4-enoic acid (3). The tripeptide fragment was prepared from β-tyrosine derivative 6, Boc-2-bromoabrine (8)