1620084-69-6

Basic information

• Product Name: 6,6-dimethyl-2-(trifluoromethanesulfonyloxy)-1-cyclohexenecarboxaldehyde
• Synonyms: 6,6-dimethyl-2-(trifluoromethanesulfonyloxy)-1-cyclohexenecarboxaldehyde
• CAS NO: 1620084-69-6
• Molecular Weight: 286.272
• Mol File: 1620084-69-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6,6-dimethyl-2-(trifluoromethanesulfonyloxy)-1-cyclohexenecarboxaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6-dimethyl-2-(trifluoromethanesulfonyloxy)-1-cyclohexenecarboxaldehyde(1620084-69-6)
• EPA Substance Registry System: 6,6-dimethyl-2-(trifluoromethanesulfonyloxy)-1-cyclohexenecarboxaldehyde(1620084-69-6)

Safety Data

• Hazardous Substances Data: 1620084-69-6(Hazardous Substances Data)

Upstream product

• 1620084-68-5 2-(hydroxymethyl)-3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate 
• 1257045-68-3 ethyl {6,6-dimethyl-2-(trifluoromethanesulfonyloxy)cyclohexene-1-yl}carboxylate 
• 2979-10-4 ethyl 2,2-dimethyl-6-oxocyclohexane-1-carboxylate 

Downstream Products

• 1620084-70-9 (2E,4E)-3-methyl-5-{6,6-dimethyl-2-(trifluoromehtanesulfonyloxy)}-2,4-pentadienoicacid ethyl ester 
• 4759-48-2 13-cis-retinoic acid 
• 1620084-71-0 (2E,4E)-3-methyl-5-{6,6-dimethyl-2-(trifluoromethanesulfonyloxy)-1-cyclohexenyl}-2,4-pentadien-1-ol 
• 1620084-72-1 (2E,4E)-3-methyl-5-{6,6-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-1-cyclohexenyl}-2,4-pentadienol 
• 1620084-73-2 (2E,4E)-3-methyl-5-{6,6-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-1-cyclohexenyl}-2,4-pentadienal 
• 1620084-74-3 (2E,4E,6E,8E)-3,7-dimethyl-9-{6,6-dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-1-cyclohexenyl}-2,4,6,8-nonatetraenoicacid ethyl ester 

Relevant articles and documents

Cut and sew: Benzofuran-ring-opening enabled cyclopentenone ring formation

A facile approach to the fully substituted cyclopentenones involving an unprecedented benzofuran-ring-opening is described. The cleavage of a benzofuran endocyclic C2-O bond proceeded smoothly in the absence of any transition metal catalyst or highly reactive organometallic reagent. Such benzofuran-ring-opening is delicately incorporated into an acid-catalyzed cascade process, orchestrating a novel synthetic strategy for complex cyclopentenones with excellent yields and diastereoselectivities. This journal is