162191-07-3

Basic information

• Product Name: Methyl 2,3-di-O-benzyl-4-O-(p-fluorophenoxy)-thionocarbonyl-6-O-triphenylmethyl-α-D-glucopyranoside
• Synonyms: Methyl 2,3-di-O-benzyl-4-O-(p-fluorophenoxy)-thionocarbonyl-6-O-triphenylmethyl-α-D-glucopyranoside
• CAS NO: 162191-07-3
• Molecular Weight: 770.919
• Mol File: 162191-07-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl 2,3-di-O-benzyl-4-O-(p-fluorophenoxy)-thionocarbonyl-6-O-triphenylmethyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,3-di-O-benzyl-4-O-(p-fluorophenoxy)-thionocarbonyl-6-O-triphenylmethyl-α-D-glucopyranoside(162191-07-3)
• EPA Substance Registry System: Methyl 2,3-di-O-benzyl-4-O-(p-fluorophenoxy)-thionocarbonyl-6-O-triphenylmethyl-α-D-glucopyranoside(162191-07-3)

Safety Data

• Hazardous Substances Data: 162191-07-3(Hazardous Substances Data)

Upstream product

• 20231-38-3 (2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)tetrahydro-6-methoxy-2-((trityloxy)methyl)-2H-pyran-3-ol 
• 42908-73-6 4-fluorophenyl chlorothionoformate 
• 162191-08-4 Methyl 2,3-di-O-benzyl-4-O-methyloxalyl-6-O-triphenylmethyl-α-D-glucopyranoside 

Downstream Products

• 108164-50-7 Methyl 2,3-di-O-benzyl-4-deoxy-α-D-xylo-hexopyranoside 
• 162191-09-5 Methyl 2,3-di-O-benzyl-4-deoxy-6-O-triphenylmethyl-α-D-xylo-hexopyranoside 

Relevant articles and documents

NUCLEOPHILIC SUBSTITUTION VERSUS RADICAL REACTION FOR CARBOHYDRATES DEOXYGENATION: APPLICATION AT C-4 OF METHYL-α-D-GLUCOPYRANOSIDE DERIVATIVES

Two methods for deoxygenation at C-4 of methyl 2,3-di-O-benzyl-α-D-glucopyranoside are reported.The first one involves nucleophilic displacement of a secondary methane sulfonate by lithium triethylborohydride to afford methyl 2,3-di-O-benzyl-4-deoxy-α-D-x