1624333-35-2Relevant articles and documents
Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(i) trifluoromethanethiolate and selectfluor
He, Bin,Xiao, Zhiwei,Wu, Hao,Guo, Yong,Chen, Qing-Yun,Liu, Chao
, p. 880 - 883 (2017/01/13)
A straightforward silver-mediated oxidative decarboxylative radical trifluoromethylthiolation reaction of aliphatic carboxylic acid is described. This reaction operates under mild conditions and allows the synthesis of various valuable alkyltrifluoromethylthioethers from abundant alkyl carboxylic acids and convenient nucleophilic AgSCF3 reagent. It provides a practical and efficient approach for the preparation of alkyltrifluoromethylthioethers.
Direct trifluoromethylthiolation of unactivated C(sp3)-H using silver(I) trifluoromethanethiolate and potassium persulfate
Wu, Hao,Xiao, Zhiwei,Wu, Junhui,Guo, Yong,Xiao, Ji-Chang,Liu, Chao,Chen, Qing-Yun
supporting information, p. 4070 - 4074 (2015/03/30)
A practical and efficient method for the direct trifluoromethylthiolation of unactivated C(sp3)-H bonds by AgSCF3/K2S2O8 under mild conditions is described. The reaction has a good functional-group tolerance and good selectivity. Initial mechanistic investigations indicate that the reaction may involve a radical process in which K2S2O8 plays key roles in both the activation of the C(sp3)-H bond and the oxidation of AgSCF3.