16247-35-1

Basic information

• Product Name: 2-(4-methoxyphenyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene
• CAS NO: 16247-35-1
• Molecular Weight: 242.361
• Mol File: 16247-35-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxyphenyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxyphenyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene(16247-35-1)
• EPA Substance Registry System: 2-(4-methoxyphenyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene(16247-35-1)

Safety Data

• Hazardous Substances Data: 16247-35-1(Hazardous Substances Data)

Upstream product

• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 578006-87-8 (1R,2S,4R)-2-(4-methoxyphenyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol 
• 76-22-2 Camphor 
• 60-29-7 diethyl ether 

Downstream Products

• 4488-58-8 4-(1,7,7-trimethylbicyclo[2.2.1]hept-exo-2-yl)phenol 
• 63785-90-0 p-Bornylanisol 

Relevant articles and documents

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Stereo- and regioselectivity in dynamic gas-phase thermoisomerization (DGPTI): Novel route to α-campholanic acid and derivatives

(Matrix presented) Dynamic gas-phase thermoisomerization (DGPTI) of (-)-2-phenylisoborneols effects stereo- and regioselective ring opening under formation of (+)-trans-α-campholanic acid derivatives. Similarly, (-)-α-2-phenylfenchol underwent under DGPTI conditions ring opening to (-)-fencholic acid derivatives. In both cases, DGPTI led to cleavage of the weakest bond in the isomeric bicyclic structures. A reaction mechanism involving a diradical intermediate is supported by a deuterium labeling study.