162898-59-1

Basic information

• Product Name: [TiCl(CH₃Si(Si(CH₃)2NC₆H₄CH₃)3)]
• Synonyms: [TiCl(CH₃Si(Si(CH₃)2NC₆H₄CH₃)3)]
• CAS NO: 162898-59-1
• Molecular Weight: 616.337
• Mol File: 162898-59-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [TiCl(CH₃Si(Si(CH₃)2NC₆H₄CH₃)3)](CAS DataBase Reference)
• NIST Chemistry Reference: [TiCl(CH₃Si(Si(CH₃)2NC₆H₄CH₃)3)](162898-59-1)
• EPA Substance Registry System: [TiCl(CH₃Si(Si(CH₃)2NC₆H₄CH₃)3)](162898-59-1)

Safety Data

• Hazardous Substances Data: 162898-59-1(Hazardous Substances Data)

Upstream product

• 31011-57-1 tetrachlorobis(tetrahydrofuran)titanium(IV) 

Downstream Products

• 1064-10-4 hexaphenylditin 

Relevant articles and documents

Tripodal Amides Containing a Totally Silicon-Based Ligand Framework

A novel type of tripodal amido ligand with a totally silicon-based (trisilylsilane-derived framework has been synthesized and coordinated to tetravalent titanium and zirconium.The key compound in the ligand synthesis is the chlorosilane H3CSi3 (2) which upon condensation with a range of primary amines R-NH2 (R = aryl, alkyl) yields the amino-functionalized ligand precursors H3CSi3 (3a-e).Their corresponding trilithium salts have been found to be the appropriate amide transfer reagents in the subsequent syntheses of the transition metal complexes.Single-crystal X-ray structure analyses of the trilithium triamide H3CSi3 (4a) and the Ti complex H3CSi3TiBr (5b) have established their respective adamantane- and bicyclooctane-related cage structures. - Key Words: Trisilylsilanes/ Tripodal ligands/ Amido complexes