163169-29-7

Basic information

• Product Name: (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%
• Synonyms: (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%;(S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine;(S,S)-ip-FOXAP;(2S)- 1-[(4S)-4,5-dihydro-4-(1-Methylethyl)-2-oxazolyl]-2-(diphenylphosphino)-Ferrocene;(S,S)-[2-(4-Isopropyl-2-oxazolinyl)ferrocenyl]diphenylphosphine, 97%;(S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine,97%;(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline ;(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline 97%
• CAS NO: 163169-29-7
• Molecular Formula: C₂₈H₂₈FeNOP
• Molecular Weight: 475.31
• Product Categories: Chiral Phosphine;PHOX Series
• Mol File: 163169-29-7.mol
• Article Data: 1

Chemical Properties

• Melting Point: 158-162℃
• Appearance: Yellow to brown/Crystalline Powder or Crystals
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive: Air Sensitive
• CAS DataBase Reference: (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%(CAS DataBase Reference)
• NIST Chemistry Reference: (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%(163169-29-7)
• EPA Substance Registry System: (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%(163169-29-7)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 163169-29-7(Hazardous Substances Data)

Usage

Description

(S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% is a complex organic compound with a unique structure that features a ferrocenyl core, diphenylphosphine group, and an isopropyloxazoline moiety. (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% is characterized by its high purity (minimum 97%) and is known for its potential applications in various fields due to its unique properties.

Uses

Used in Catalyst Industry:
(S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% is used as a chiral ligand for the synthesis of metal complexes, particularly for rhodium, iridium, ruthenium, and osmium. These metal complexes are essential in various catalytic processes, such as asymmetric hydrogenation, hydroformylation, and olefin polymerization. The chiral nature of the ligand allows for the creation of enantiomerically pure products, which are crucial in the pharmaceutical and agrochemical industries.
Used in Pharmaceutical Industry:
The compound can also be utilized in the development of novel pharmaceuticals, particularly in the synthesis of chiral drugs. The unique structure of (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% enables it to form stable complexes with metal ions, which can be used as catalysts in the synthesis of chiral molecules with potential therapeutic applications.
Used in Material Science:
In the field of material science, (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% can be employed in the development of new materials with unique properties. The compound's ability to form stable metal complexes can be exploited in the design of advanced materials with applications in areas such as electronics, sensors, and energy storage.
Used in Research and Development:
Due to its unique structure and potential applications, (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% is a valuable compound for research and development purposes. It can be used as a starting material or a key intermediate in the synthesis of more complex molecules with potential applications in various industries.

Upstream product

• 297163-59-8 (R)-3,5-dihydrodinaphtho[2,1-c:1',2'-e]selenepin 4-oxide 
• 1065474-88-5 rac-[2-(4-isopropyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine 

Downstream Products

• 541540-70-9 [2-(4-isopropyl-2-oxazoline-2-yl)ferrocenyl]diphenylphosphine 

Relevant articles and documents

Kinetic resolution of racemic ferrocenylphosphine compounds by enantioselective oxidation using cyclic selenoxides having a chiral ligand

Cyclic selenoxides having an optically active binaphthyl skeleton work as the reagents for enantioselective oxidation of phosphines to the corresponding phosphine oxides. Treatment of a racemic 2-oxazolin-2-ylferrocenylphosphine with one of the selenoxides in carbon tetrachloride in the presence of phenol affords the corresponding phosphine oxide together with the unreacted starting phosphine, both with moderate enantioselectivities (the phosphine oxide, up to 13% ee; the phosphine, up to 29% ee).