163235-64-1

Basic information

• Product Name: (CO)3Fe(CH(O(CH₂)3)NC(O)C(CH₃)CHCHC₆H₅)
• CAS NO: 163235-64-1
• Molecular Weight: 383.184
• Mol File: 163235-64-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CO)3Fe(CH(O(CH₂)3)NC(O)C(CH₃)CHCHC₆H₅)(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)3Fe(CH(O(CH₂)3)NC(O)C(CH₃)CHCHC₆H₅)(163235-64-1)
• EPA Substance Registry System: (CO)3Fe(CH(O(CH₂)3)NC(O)C(CH₃)CHCHC₆H₅)(163235-64-1)

Safety Data

• Hazardous Substances Data: 163235-64-1(Hazardous Substances Data)

Upstream product

• 5638-63-1 5,6-dihydro-4H-[1,3]oxazine 
• 821775-44-4 tricarbonyl(3-methyl-5-phenyl-1-oxapenta-1,2,4-triene)iron⁽⁰⁾ 

Relevant articles and documents

Reactions of tricarbonyl(vinylketene)iron(0) complexes with imines

Tricarbonyl(vinylketene)iron(0) complex 1 underwent reaction with a variety of imines to produce η3-allyl-η1-alkyl iron complexes 4-7, resulting from insertion of the imine into an iron-acyl carbonyl bond. Complex 4 was characterized by X-ray crystallography, confirming the proposed structure: monoclinic, space group P21/n, a = 11.098(2) A?, b = 9.837(2) A?, c = 16.531(3) A?, β = 108.67(3) A?, Z = 4, R = 0.0443, and Rw = 0.0669 for the 2862 reflections observed. Oxidative degradation of these complexes with I2/Me3NO produced 2-pyridones or unsaturated δ-lactams, along with minor amounts of β-lactams.