163580-29-8Relevant articles and documents
Synthesis of C-disaccharide analogues of the α-D-arabinofuranosyl- (1→5)-α-D-arabinofuranosyl motif of mycobacterial cell walls via alkynyl intermediates
Aslam, Tashfeen,Fuchs, Michael G. G.,Le Formal, Adeline,Wightman, Richard H.
, p. 3249 - 3252 (2007/10/03)
Two C-glycosides related to the recurrent α-D-arabinofuranosyl- (1→5)-α-D-arabinofuranosyl structural motif of mycobacterial arabinan have been prepared by routes involving acetylenic intermediates.
Synthesis of C-glycofuranosides by the stereoselective reduction of hemiacetals
Calzada, Eguzkine,Clarke, Catherine A.,Roussin-Bouchard, Christine,Wightman, Richard H.
, p. 517 - 518 (2007/10/02)
Reaction of protected glycofuranolactones with organolithium reagents and reduction of the resultant hemiacetals with triethylsilane-boron trifluoride gives a stereocontrolled route to C-glycofuranosides, with hydride delivery occurring cis-to an adjacent