1639427-95-4

Basic information

• Product Name: C₁₅H₁₆N₂O₄
• CAS NO: 1639427-95-4
• Molecular Weight: 288.303
• Mol File: 1639427-95-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₆N₂O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₆N₂O₄(1639427-95-4)
• EPA Substance Registry System: C₁₅H₁₆N₂O₄(1639427-95-4)

Safety Data

• Hazardous Substances Data: 1639427-95-4(Hazardous Substances Data)

Upstream product

• 3128-06-1 5-ketohexanoic acid 
• 67-56-1 methanol 
• 59-88-1 phenylhydrazine hydrochloride 
• 52128-61-7 methyl 4,4-dimethoxypentanoate 

Relevant articles and documents

From renewable levulinic acid to a diversity of 3-(Azol-3-yl)propanoates

Efficient heterocyclization of methyl 7,7,7-trifluoro-4-methoxy-6-oxo-4- heptenoate and methyl 7,7,7-trichloro-4-methoxy-6-oxo-4-heptenoate into isoxazole and pyrazole derivatives that represent a new type of glutamate-like 3-(trihalomethylated-1,2-azol-3-yl)propanoate is reported. Preparation of the key methyl 7,7,7-trihalo-4-methoxy-6-oxohept-4-enoate precursors from levulinic acid is also described. The synthetic potential of this synthetic protocol was indicated by the production of several methyl and ethyl 3-(isoxazol-3-yl) propanoates and 3-(1H-pyrazol-3-yl)propanoates, and the respective acid derivatives, in good (70-95%) yields. The crystal structure for ethyl 5-(3-ethoxy-3-oxopropyl)-1H-pyrazole-3-carboxylate (10c) has been determined by monocrystal X-ray diffraction analysis. The N-H...H intermolecular hydrogen bonds join the molecules into catamer.