1639441-07-8

Basic information

• Product Name: C₁₈H₁₈N₂O₄
• Synonyms: C₁₈H₁₈N₂O₄
• CAS NO: 1639441-07-8
• Molecular Weight: 326.352
• Mol File: 1639441-07-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₁₈N₂O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₁₈N₂O₄(1639441-07-8)
• EPA Substance Registry System: C₁₈H₁₈N₂O₄(1639441-07-8)

Safety Data

• Hazardous Substances Data: 1639441-07-8(Hazardous Substances Data)

Upstream product

• 40061-45-8 1-phenyl-2-(pyrazin-2-yl)ethanone 

Downstream Products

• 1639441-15-8 C₁₆H₁₄N₂O 

Relevant articles and documents

Direct asymmetric dearomatization of pyridines and pyrazines by iridium-catalyzed allylic amination reactions

The first iridium-catalyzed intramolecular asymmetric allylic dearomatization reaction of pyridines and pyrazines has been realized. 2,3-Dihydroindolizine and 6,7-dihydropyrrolo[1,2-a]pyrazine derivatives were obtained with excellent yields and enantioselectivity. This methodology features dearomatization by direct N-allylic alkylation of pyridines or pyrazines under mild reaction conditions. Getting 'rid' of aromaticity: An iridium-catalyzed intramolecular asymmetric allylic dearomatization reaction converts pyridines and pyrazines (not shown) into 2,3-dihydroindolizine and 6,7-dihydropyrrolo[1,2- a]pyrazine derivatives with excellent yields and enantioselectivities. The dearomatization proceeds by direct N-allylic alkylation of pyridines or pyrazines under mild reaction conditions.