164020-64-8

Basic information

• Product Name: N-benzylidene-2-bromobenzeneethanamine
• Synonyms: N-benzylidene-2-bromobenzeneethanamine
• CAS NO: 164020-64-8
• Molecular Weight: 288.187
• Mol File: 164020-64-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzylidene-2-bromobenzeneethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzylidene-2-bromobenzeneethanamine(164020-64-8)
• EPA Substance Registry System: N-benzylidene-2-bromobenzeneethanamine(164020-64-8)

Safety Data

• Hazardous Substances Data: 164020-64-8(Hazardous Substances Data)

Upstream product

• 65185-58-2 2-(2-bromophenyl)ethanamine 
• 100-52-7 benzaldehyde 

Downstream Products

• 22990-19-8 1-phenyl-1,2,3,4-tetrahydroisoquinoline 

Relevant articles and documents

Free-Radical Chemistry of Imines

Aryl radicals bearing an aldimino functional group as part of an ortho substituent cyclized by addition to C and/or N of the imino group.When the choice was between 5-exo closure to C and 6-endo closure to N, the former predominated.However, 6-endo closure to C predominated over 5-exo cyclization to N in isomeric imines.Absolute values of cyclization rate constants were determined and an explanation for the unusual 6-endo preference is offered.Chiral induction in 6-endo cyclization to C of an aldimine from D-glyceraldehyde acetonide was observed, and its sense was determined.