16411-16-8

Basic information

• Product Name: Benzene, 1-chloro-4-(ethenylthio)-
• CAS NO: 16411-16-8
• Molecular Formula: C8H7ClS
• Molecular Weight: 170.663
• Mol File: 16411-16-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(ethenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(ethenylthio)-(16411-16-8)
• EPA Substance Registry System: Benzene, 1-chloro-4-(ethenylthio)-(16411-16-8)

Safety Data

• Hazardous Substances Data: 16411-16-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 123-38-6 propionaldehyde 
• 74-85-1 ethene 
• 106-54-7 p-Chlorothiophenol 
• 928-57-4 2-chloroethyl thiocyanate 
• 7270-47-5 4-chlorophenylmagnesium iodide 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 75-20-7 calcium carbide 
• 106-39-8 bromochlorobenzene 
• 33735-40-9 2,2-diphenyl-1,3-oxathiolane 
• 106-93-4 ethylene dibromide 
• 7205-69-8 ethyl (4-chloro)phenyl sulfoxide 
• 933-01-7 4-chloro-benzenesulfenyl chloride 
• 637-87-6 1-Chloro-4-iodobenzene 

Downstream Products

• 60142-22-5 (Z)-4-(4-chlorophenylthio)-1,1,1-trifluorobut-3-en-2-one 
• 60142-23-6 (Z)-1,1,1-Trichloro-4-(4-chloro-phenylsulfanyl)-but-3-en-2-one 
• 120181-31-9 C₁₄H₁₁BrCl₂S₂ 
• 120166-40-7 C₁₄H₁₁BrCl₂SSe 
• 63383-26-6 1-chloro-4-(vinylsulfinyl)benzene 
• 66823-40-3 <(p-chlorophenyl)sulfenyl>acetylene 
• 121954-81-2 1-((E)-2-Bromo-ethenesulfonyl)-4-chloro-benzene 
• 121954-80-1 Z-β-bromovinyl p-chlorophenyl sulfide 
• 121954-80-1 E-β-bromovinyl p-chlorophenyl sulfide 
• 120166-45-2 1-methoxy-1-p-chlorophenylthio-2-(p-bromophenylthio)ethane 
• 217434-85-0 (+)-1-chloro-4-(vinylsulfinyl)benzene 
• 1262638-56-1 (-)-1-chloro-4-(vinylsulfinyl)benzene 
• 1262638-60-7 (1S,2S,4S)-2-(4-chlorophenylsulfinyl)-7-oxabicyclo[2.2.1]hept-5-ene 
• 1262638-75-4 (1S,2R,4S)-2-(4-chlorophenylsulfinyl)-7-oxabicyclo[2.2.1]hept-5-ene 

Relevant articles and documents

Extended Pummerer fragmentation mediated by carbon dioxide and cyanide

Pummerer rearrangement reactions generate sulfur (II) oxidation state from sulfur (IV) starting materials in the presence of activating reagents. We found unprecedented transformation of vinyl sulfoxide; disulfide formation reactions mediated by atmospheric pressure of carbon dioxide in extended Pummerer rearrangement reactions. Only under CO2 atmosphere, we observed moderate to high yields of disulfide starting from sulfur (IV) starting materials. Investigations on the reaction mechanism revealed that the degradation of the starting materials and the products was significant in the absence of CO2. Further evidence for the suggested reaction mechanism was obtained by a cross-over experiment and a radical trapping reagent.

Difluoro- and trifluoro diazoalkanes-complementary approaches in batch and flow and their application in cycloaddition reactions

Herein we report on applications of fluorinated diazoalkanes in cycloaddition reactions, with the emphasis on studying subtle differences between diverse fluorinated diazo compounds. These differences led to two major synthetic protocols in batch and flow that allow the safe and scalable synthesis of fluoroalkyl-, sulfone-substituted pyrazolines.

An efficient metal-free pathway to vinyl thioesters with calcium carbide as the acetylene source

Chemical reactions involving high-pressure acetylene are not easily performed in a standard laboratory setup. The risk of explosion and technical difficulties drastically complicate the equipment and greatly increase the cost. In this study, we propose th