164400-28-6

Basic information

• Product Name: bis(μ-chloro)bis(1-(4-nitrophenyl)-η(3)-allyl)dipalladium
• CAS NO: 164400-28-6
• Molecular Weight: 608.082
• Mol File: 164400-28-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(μ-chloro)bis(1-(4-nitrophenyl)-η(3)-allyl)dipalladium(CAS DataBase Reference)
• NIST Chemistry Reference: bis(μ-chloro)bis(1-(4-nitrophenyl)-η(3)-allyl)dipalladium(164400-28-6)
• EPA Substance Registry System: bis(μ-chloro)bis(1-(4-nitrophenyl)-η(3)-allyl)dipalladium(164400-28-6)

Safety Data

• Hazardous Substances Data: 164400-28-6(Hazardous Substances Data)

Upstream product

• 52522-40-4 tris(dibenzylideneacetone)dipalladium⁽⁰⁾ * CHCl₃ 
• 1507-90-0 p-nitrocinnamyl chloride 

Downstream Products

• 189766-71-0 (1,2-bis(diphenylphosphino)ethane)(η(3)-1-(4-nitrophenyl)allyl)palladium tetrafluoroborate 

Relevant articles and documents

(1,2-Bis(diphenylphosphino)ethane)(η3-1-arylallyl)palladium tetrafluoroborates. Distribution of the positive charge density by correlation of NMR chemical shifts with Hammett substituent constants

13C NMR differences of chemical shifts (δX - δH) of allyl carbon atoms in a series of (1,2-bis(diphenylphosphino)ethane)(η 3-1-(4-X-phenyl)allyl)palladium tetrafluoroborates, X ranging from NO2 to OMe, correlate very well (r > 0.994) with σ Hammett constants. However, 31P NMR differences of the ligand cis and trans phosphorus atoms correlate well with σ and with σ+, respectively. These data indicate that the positive charge density of the cation is localized mainly in the P-Pd-P region.