16453-20-6

Basic information

• Product Name: <4,4-D2>Cyclohexanon
• Synonyms: <4,4-D2>Cyclohexanon
• CAS NO: 16453-20-6
• Molecular Weight: 100.129
• Mol File: 16453-20-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: <4,4-D2>Cyclohexanon(CAS DataBase Reference)
• NIST Chemistry Reference: <4,4-D2>Cyclohexanon(16453-20-6)
• EPA Substance Registry System: <4,4-D2>Cyclohexanon(16453-20-6)

Safety Data

• Hazardous Substances Data: 16453-20-6(Hazardous Substances Data)

Upstream product

• 15313-92-5 C₈H₁₃⁽²⁾HO₃ 
• 4746-97-8 cyclohexanedione monoethylene ketal 
• 111616-19-4 C₁₈H₂₅⁽²⁾HO₅S 
• 111616-20-7 C₁₁H₁₈⁽²⁾H₂O₂ 
• 13482-22-9 4-hydroxycyclohexanone 
• 60739-53-9 4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone 
• 21273-05-2 cyclohexanol-γ-d2 

Downstream Products

• 43087-26-9 2,2,4,4,6,6-hexadeuterio-cyclohexanone 

Relevant articles and documents

Hydrogen Transfer Reactions, 19. - The Catalysis of Hydrogen Transfer and 1,5-H Shift by Rhodium(III) Chloride in Homogeneous Organic Systems

In homogeneous solution, partly in the presence of a phase-transfer catalyst, rhodium(III) chloride catalyzes the disproportionation of 1,3-cyclohexadiene and to a lesser extent 1,5-H shifts.In the start phase the catalyst is reduced to the active monovalent state.In these catalytic systems the dehydrogenation proceeds stereoselectively. - This was shown by tracer experiments and isotopes effects using deuterated 1,3-cyclohexadienes 1a-d, which were synthesized with high isotopomeric purity.Key Words: Rhodium chloride / Hydrogen transfer / Deuterated 1,3-cyclohexadienes / Isotope effects

Synthesis of some symmetrically deuterated cyclohexanones

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