1647097-04-8Relevant articles and documents
Tert-butyl nitrite mediated regiospecific nitration of (E)-azoarenes through palladium-catalyzed directed C - H activation
Majhi, Biju,Kundu, Debasish,Ahammed, Sabir,Ranu, Brindaban C.
supporting information, p. 9862 - 9866 (2014/08/18)
An efficient protocol for the Pd-catalyzed regiospecific ortho-nitration of (E)-azoarenes has been achieved for the first time using tBuONO as a nitrating agent under atmospheric oxygen. A series of both symmetrical and unsymmetrical azoarenes were nitrated efficiently by this procedure providing excellent chemo- and regioselectivity and compatibility with a broad array of functional groups.