1648-06-2Relevant articles and documents
Fluoride-assisted trifluoromethylation of aromatic thiones with (trifluoromethyl)trimethylsilane
Large-Radix, Sylvie,Billard, Thierry,Langlois, Bernard R.
, p. 147 - 149 (2003)
In the presence of a stoichiometric amount of Bu4NF·3H2O, (trifluoromethyl)trimethylsilane reacts with aromatic thiones in both thiophilic and carbophilic ways to deliver, in medium yield, a mixture of (trifluoromethylthio)diarylmethane and 1,1-diaryl-2,2,2-trifluoroethanethiol, the former product being the major one.
Aryl gem-Difluorovinyl Pinacolboronates: Synthesis and Utility for Suzuki-Miyaura Coupling Reaction
Zhou, Jun,Jiang, Bingyao,Guo, Ming,Sumii, Yuji,Shibata, Norio
, p. 1439 - 1442 (2020/12/01)
The synthesis of unstable aryl difluorovinyl pinacolboronates was achieved by the dehydrofluorination of α-trifluoromethyl arylmethyl pinacolboronates with LDA. These aryl difluorovinyl pinacolboronates can be used for Suzuki-Miyaura coupling with various
Consecutive cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate with boronic acids: Efficient synthesis of 1,1-diaryl-2,2-difluoroethenes
Kim, Ju Hee,Choi, Su Jeong,Jeong, In Howa
supporting information, p. 2470 - 2475 (2014/01/06)
The cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate (2) with 2 equiv of boronic acids in the presence of catalytic amounts of Pd(OAc)2 and Na2CO3 afforded the mono-coupled products 3 and 5 in high yields. The use of 4 equiv of boronic acid
