16487-65-3

Basic information

• Product Name: [(Z)-3-Pentenyl]benzene
• Synonyms: (Z)-5-Phenyl-2-pentene;[(Z)-3-Pentenyl]benzene
• CAS NO: 16487-65-3
• Molecular Formula: C₁₁H₁₄
• Molecular Weight: 146.23
• Mol File: 16487-65-3.mol
• Article Data: 32

Chemical Properties

• Boiling Point: 201.6±10.0 °C(Predicted)
• Appearance: /
• Density: 0.884±0.06 g/cm3(Predicted)
• CAS DataBase Reference: [(Z)-3-Pentenyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(Z)-3-Pentenyl]benzene(16487-65-3)
• EPA Substance Registry System: [(Z)-3-Pentenyl]benzene(16487-65-3)

Safety Data

• Hazardous Substances Data: 16487-65-3(Hazardous Substances Data)

Upstream product

• 4894-61-5 trans-but-2-enyl chloride 
• 766-04-1 benzyllithium 
• 56281-58-4 Dimethyl-dithiocarbamic acid (E)-1-benzyl-but-2-enyl ester 
• 6921-34-2 benzylmagnesium chloride 
• 104-53-0 3-phenyl-propionaldehyde 
• 594-02-5 1,1-diiodoethane 
• 15733-63-8 5-chloropentylbenzene 
• 113460-17-6 C₂₅H₂₇OP 
• 103786-13-6 erythro-3-diphenylphosphinoyl-5-phenylpentan-2-ol 
• 1754-88-7 ethylenetriphenylphosphorane 
• 37904-38-4 5-phenylpent-1-en-3-ol 
• 67-56-1 methanol 
• 76620-26-3 sodium salt of (E)-1-phenyl-3-penten-1-one N-tosylhydrazone 
• 100-39-0 benzyl bromide 

Downstream Products

• 37904-38-4 5-phenylpent-1-en-3-ol 
• 1992-50-3 1-phenylpentan-3-ol 
• 2344-71-0 5-phenylpentan-2-ol 
• 17777-31-0 6-phenylhexanenitrile 

Relevant articles and documents

METHODS OF BORYLATION AND USES THEREOF

The present invention relates, in general terms, to methods of borylation and uses thereof. In particular, the present invention provides a method of borylating an alkene compound by contacting the compound with a boron compound, a Fe pre-catalyst and a protic additive. The borylation occurs at a vicinal (β) position to an electron donating or electron withdrawing moiety of the compound.

Structural elucidation of a methylenation reagent of esters: Synthesis and reactivity of a dinuclear titanium(iii) methylene complex

Transmetallation of a zinc methylene complex [ZnI(tmeda)]2(μ-CH2) with a titanium(iii) chloride [TiCl3(tmeda)(thf)] produced a titanium methylene complex. The X-ray diffraction study displayed a dinuclear methylene structure [TiCl(tmeda)]2(μ-CH2)(μ-Cl)2. Treatment of an ester with the titanium methylene complex resulted in methylenation of the ester carbonyl to form a vinyl ether. The titanium methylene complex also reacted with a terminal olefin, resulting in olefin-metathesis and olefin-homologation. Cyclopropanation by methylene transfer from the titanium methylene proceeded by use of a 1,3-diene. The mechanistic study of the cyclopropanation reaction by the density functional theory calculations was also reported.

A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins

An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described. A wide variety of trans-2-olefins bearing various functional groups can be obtained with high regio- A nd stereoselectivity under mild reaction conditions. The ligand is crucial for the reaction.