16510-84-2

Basic information

• Product Name: Cyclohexane, 1,2-dibromo-1-methyl-, trans-
• CAS NO: 16510-84-2
• Molecular Formula: C7H12Br2
• Molecular Weight: 255.98
• Mol File: 16510-84-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1,2-dibromo-1-methyl-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1,2-dibromo-1-methyl-, trans-(16510-84-2)
• EPA Substance Registry System: Cyclohexane, 1,2-dibromo-1-methyl-, trans-(16510-84-2)

Safety Data

• Hazardous Substances Data: 16510-84-2(Hazardous Substances Data)

Upstream product

• 75-21-8 oxirane 
• 591-49-1 1-methylcyclohex-1-ene 
• 1713-33-3 1,2-epoxy-1-methylcyclohexane 
• 67-56-1 methanol 
• 64-17-5 ethanol 
• 82166-21-0 methyl cyclohexane 

Downstream Products

• 109458-85-7 3-chloro-1-methylcyclohex-1-ene 
• 82166-21-0 methyl cyclohexane 
• 590-66-9 1,1-dimethylcyclohexane 
• 1489-57-2 2-methylcyclohexa-1,3-diene 

Relevant articles and documents

Revisiting the bromination of c-h bonds with molecular bromine by using a photo-microflow system

The photobromination of C-H bonds by using molecular bromine was reinvestigated under microfluidic conditions. The continuous-flow method suppressed the production of dibrominated compounds and effectively produced the desired monobrominated products with high selectivity. Rapid bromination of benzylic substrates containing a photoaffinity azide group was achieved without any decomposition. Go with the (micro)flow: Photobromination of C-H bonds by using molecular bromine under microfluidic conditions has been investigated (see scheme). The continuous-flow method suppressed the production of dibrominated compounds and effectively produced the desired monobrominated compounds with high selectivity. Rapid bromination of benzylic substrates containing a photoaffinity azide group was achieved without any decomposition.

Regio-and stereoselective hydroxybromination and dibromination of olefins using ammonium bromide and oxone

An efficient protocol for the synthesis of vicinal bromohydrins and dibromides from olefins is presented. Various olefins are regio-and stereoselectively hydroxybrominated and dibrominated with anti fashion, following Markonikov's rule, using eco-friendly, non-toxic, and stable reagents such as NH4Br and oxone in CH3CN/H2O (1:1) and CH3CN without employing catalyst in moderate to excellent yields. Bromohydrins are formed instantaneously.

Cohalogenation of alkenes in ethylene oxide: Efficient methodology for the preparation of allyl vinyl ether precursors of γ,δ-unsaturated aldehydes

An investigation of the cohalogenation-dehydrohalogenation sequence as a method for the preparation of allyl vinyl ethers from simple olefins has been performed. Alkenes 1a-k react with bromide or chloride in the presence of ethylene oxide at -80°C to for