16522-52-4

Basic information

• Product Name: Phenol, 2-(diphenylphosphinyl)-
• CAS NO: 16522-52-4
• Molecular Formula: C18H15O2P
• Molecular Weight: 294.29
• Mol File: 16522-52-4.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(diphenylphosphinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(diphenylphosphinyl)-(16522-52-4)
• EPA Substance Registry System: Phenol, 2-(diphenylphosphinyl)-(16522-52-4)

Safety Data

• Hazardous Substances Data: 16522-52-4(Hazardous Substances Data)

Usage

General Description

Phenol, 2-(diphenylphosphinyl)- is a chemical compound with the formula (C6H5)2P(O)OH. It belongs to the class of organophosphorus compounds and is commonly used as a ligand in organometallic chemistry. It has been found to exhibit a wide range of biological activities, including antifungal, antibacterial, and antiviral properties. Phenol, 2-(diphenylphosphinyl)- has also been studied for its potential application in the synthesis of pharmaceuticals and agrochemicals. Overall, phenol, 2-(diphenylphosphinyl)- is a versatile chemical with diverse applications in both the laboratory and industrial settings.

Upstream product

• 1706-96-3 phenyl diphenylphosphinate 
• 533-58-4 2-Iodophenol 
• 603-35-0 triphenylphosphine 
• 844468-42-4 (2-hydroxyphenyl)triphenylphosphonium bromide 
• 95-56-7 2-hydroxybromobenzene 
• 15979-14-3 bis[3,5-bis(trifluoromethyl) phenyl]phosphine oxide 
• 622-79-7 benzyl azide 
• 1707-03-5 diphenyl-phosphinic acid 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 578-57-4 2-bromoanisole 
• 51986-54-0 2-(methoxy)phenyl-diphenylphosphine oxide 
• 1499-21-4 Diphenylphosphinic chloride 
• 4559-70-0 Diphenylphosphine oxide 
• 4203-50-3 2-phenoxytetrahydropyran 

Downstream Products

• 51986-54-0 2-(methoxy)phenyl-diphenylphosphine oxide 
• 77746-36-2 2-[2-(diphenylphosphoryl)phenoxy]ethanol 
• 381711-01-9 2-diphenylphosphanyl(oxide)-6-tert-butyl-phenol 
• 1208539-48-3 2,4-di-tert-butyl-6-diphenylphosphinoyl-phenol 
• 60254-03-7 4-tert-butyl-2-(diphenyl-phosphinoyl)-phenol 
• 119494-80-3 1,14-bis[2-(diphenylphosphoryl)phenoxy]-3,6,9,12-tetraoxatetradecane 
• 119494-79-0 1,11-bis<2-(diphenylphosphinoyl)phenoxy>-3,6,9-trioxaundecane 
• 100697-28-7 1,8-bis[2-(diphenylphosphinyl)]phenoxy-3,6-dioxaoctane 
• 1200959-54-1 2-(diphenylphosphano)phenol-borane complex 

Relevant articles and documents

Revealing Silylation of C(sp2)/C(sp3)–H Bonds in Arylphosphines by Ruthenium Catalysis

The first aromatic C?H silylation between arylphosphines and hydrosilanes enabled by a ruthenium complex has been developed. The excellent ortho-selectivity results from a four-membered metallacyclic intermediate involving phosphorus chelation. The develo

Generation of arynes by selective cleavage of a carbonphosphorus bond of o-(diarylphosphinyl)aryl triflates using a grignard reagent

A novel method for generating arynes, including disubsti-tuted benzynes and a dehydrophenoxathiin, is reported. The treatment of easily synthesizable o-(diarylphosphinyl)aryl triflates having two electron-deficient aromatic groups on the phosphorus atom with a phenyl Grignard reagent triggered the efficient generation of arynes by selective cleavage of a carbonphosphorus bond.

Insertion of Arynes into P-O Bonds: One-Step Simultaneous Construction of C-P and C-O Bonds

The insertion of arynes into P-O bonds for the preparation of o-hydroxy-substituted arylphosphine oxides, -phosphinates, and -phosphonates is described. This novel reaction leads to the simultaneous formation of C-P and C-O bonds in one step with good yie